Số phát hành: Số 1 - Tháng 1 - 2022Hóa học - Công nghệ thực phẩm
Preparation of Bimetallic Co-Cu Supported on Activated Carbon Catalyst for Selective Production of 2,5-Furandicarboxylic Acid
Xuất bản: tháng 7 30, 2026
Tóm tắt
The utilization of renewable resources such as biomass has been of great interest to scholars in the field of green chemistry. In this study, commercial activated carbon was applied as catalyst support. The bimetallic catalyst was synthesized by the impregnation method with different ratios of cobalt to copper loading on the catalyst support. This catalyst has been used in the conversion of 5-hydroxymethylfurfural (5-HMF) by using hydrogen peroxide (H2O2) as liquid oxidant to form 2,5-furandicarboxylic acid (2,5-FDCA) through an oxidation process. Various reaction parameters such as reaction time (h), reaction temperature (0C), and catalyst loading (wt.%) on the catalytic performance were investigated. The optimal catalyst was prepared using cobalt and copper in a mass ratio of 4:1, giving high HMF conversion (greater than 99%) and 40% of FDCA selectivity at 1100C for 5 hours.
M. Sajid, X. Zhao, D. Liu. (2018). Production of 2,5-furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF): recent progress focusing on the chemical-catalytic routes. Green Chemistry, 20(24), 5427-5453.
2.
Z. Zhang, K. Deng. (2015). Recent Advances in the Catalytic Synthesis of 2,5-Furandicarboxylic Acid and Its Derivatives. ACS Catalysis, 5, 6529-6544.
3.
B. Liu, Y. Ren, Z. Zhang. (2015). Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water under mild conditions. Green Chemistry, 17(3), 1610-1617.
4.
A.A. Marianou, C.M. Michailof, A. Pineda, E.F. Iliopoulou, K.S. Triantafyllidis, A.A. Lappas. (2018). Effect of Lewis and Bronsted acidity on glucose conversion to 5-HMF and lactic acid in aqueous and organic media. Applied Catalysis A: General, 555, 75-87.
5.
C.-T. Chen, C.V. Nguyen, Z.-Y. Wang, Y. Bando, Y. Yamauchi, M.T.S. Bazziz, A. Fatehmulla, W.A. Farooq, T. Yoshikawa, T. Masuda, K.C.W. Wu. (2018). Hydrogen Peroxide Assisted Selective Oxidation of 5-Hydroxymethylfurfural in Water under Mild Conditions. ChemCatChem, 10 (2) 361-365.
6.
S. Dinh Ngo, T. Tuong Vi Tran, S. Kongparakul, P. Reubroycharoen, P. Kidkhuntod, N. Chanlek, J. Wang, G. Guan, C. Samart. (2020). Catalytic pyrolysis of Napier grass with nickel-copper core-shell bi-functional catalyst. Journal of Analytical and Applied Pyrolysis, 145 (2020) 104745.
7.
T. Theivasanthi, M. Alagar. (2010). X-Ray Diffraction Studies of Copper Nanopowder. [Online] Avalabile at https://arxiv.org/ftp/arxiv/papers/1003/1003.6068.pdf
8.
Y. Xue, S. Wang, P. Bi, G. Zhao, Y. Jin. (2019). Super-Hydrophobic Co-Ni Coating with High Abrasion Resistance Prepared by Electrodeposition. Coatings, 9(4), 232.
9.
S.M. Pawar, J. Kim, A.I. Inamdar, H. Woo, Y. Jo, B.S. Pawar, S. Cho, H. Kim, H. Im. (2016). Multi-functional reactively-sputtered copper oxide electrodes for supercapacitor and electro-catalyst in direct methanol fuel cell applications. Scientific reports, 6(1), 1-9.
10.
R. Lakra, R. Kumar, D.N. Thatoi, P.K. Sahoo, A. Soam. (2021). Synthesis and characterization of cobalt oxide (Co3O4) nanoparticles. Materials Today: Proceedings, 41(Part 2), 269-271.
11.
S. Saravanamurugan, A. Pandey, R.S. Sangwan. (2017). Biomass-Derived HMF Oxidation with Various Oxidants. In: Agarwal A., Agarwal R., Gupta T., Gurjar B. (eds) Biofuels. Green Energy and Technology (pp. 51-67). Springer, Singapore.
12.
J. Lewkowski. (2001). Synthesis, chemistry and applications of 5-hydroxymethylfurfural and its derivatives, Archive for Organic Chemistry, 2001(1), 17-54.
Cùng chuyên mục
Bài viết liên quan
Các bài trong chuyên đề «Hóa học - Công nghệ thực phẩm».
